Relationship between lattice structure and floatability of minerals

    Why do different minerals have different surface wettability, some have strong hydrophilicity and some have weak hydrophilicity, so that there is such a big difference in their floatability? This is because the hydrophilicity of the mineral surface is determined first by the physicochemical properties of the mineral surface, and its physicochemical properties are determined by the lattice structure of the chemical composition of the mineral itself.
    Any mineral is composed of ions, atoms, and molecules. When the particles of different elements form the mineral crystal, they can be in the ionic state, the atomic state, and the molecular state. The states are different, and the bonding forces formed by the different elements are different. When the mineral with the ionic lattice and the covalent lattice is broken and ground, the residual bond force exposed on the fracture surface is stronger. When the bond strength is strong, the affinity for water molecules is large, and the mineral is relatively difficult to float. When the mineral and having a molecular lattice of broken metal lattice, the residual bond strength fracture surface exposed relatively weak bond is weak affinity for water molecules is small, and therefore, the mineral is more buoyant.

    The order of floatability of minerals in water

    Floatability order

    Mineral name

    Crystal structure

    Big

    Naphthalene, paraffin, iodine , sulfur

    Molecular crystal

    in

    Graphite , molybdenum ore

    The lamellar lattice and fracture surface are dominated by molecules

    small

    Natural gold

      Pyrite, galena

    fluorite

    Calcite

    Mica

    Feldspar , quartz

    Metal lattice

      Semi-metal lattice

       Simple ion lattice

       Complex ion lattice

       Layered ion lattice

    Covalent lattice

    The table above lists the natural floatability sequence and lattice structure of some minerals in water. It can be seen that the minerals with large natural buoyancy are minerals that are not common in the flotation, and the common minerals are naturally less buoyant and need to be treated by flotation treatment to float. Therefore, from a practical point of view, the floatability of minerals should take into account various factors. For example, natural gold and heavy metal sulfides are minerals that are less buoyant in the table. Therefore, in order to improve the floatability of minerals, it is necessary to change the properties of the mineral surface so that the minerals can be selectively attached when they are in contact with the bubbles. For non-hydrophilic minerals, conditions must also be created to allow the mineral to be wetted by water.

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